Thursday, September 26, 2024

Angular Kinematics Overview

 Physics Index

Where are we going with this? The information on this page connects to standards such as:

• Gather evidence to defend the claim of Newton's first law of motion by explaining the effect that balanced forces have upon objects that are stationary or are moving at constant velocity.

•Recognize and communicate information about energy efficiency and/or inefficiency of machines used in everyday life.

Angular Kinematics Overview
(Wow… This sounds fancy!)

Angular kinematics is a way to describe something moving around a circle.  This is a lot like geometry!

It is pretty cool, though and NASA has this…

https://www.grc.nasa.gov/www/k-12/airplane/angdva.html


Angular Displacement

Angular displacement: The amount that the angle changes of from the initial position to the final position.

Angular displacement is sometimes represented by the letter phi φ. Angles are often represented by θ. And the ∆ is our good buddy to represent change of.

So we can say that φ is essentially ∆θ. 

We have established that ∆ anything is where did end up compared to where it started. For instance

∆T = Tf - Ti

∆d = df - di


So, 

∆θ = θf - θi

That should make sense, right? Back to the "sometimes a phi" thing:

φ = θf - θi

Keep in mind that "f" and "i" are only one way to indicate beginning and ending conditions. "0" and "1" are also seen and many sources use them for Angular displacement.

Source


So… 

φ = θf - θi

∆θ = θf - θi

is the same as

φ = θ1 - θ0

∆θ = θ1 - θ0 


Sample 1: A thing is at 30°. It moves to 50°. What is its angular displacement? (Ans. 20°)

Sample 2: A thing is at 0 rad. It moves to π rad. What is its angular displacement? (Ans  π rad)


How Far Did It Move

Geometry allows for some fun stuff when the angles are in radians.  Trust me on this!

In general, any angle θ measured in radians is defined by the formula

θ = s/r

where s is arc length and r is radius

that means that

∆θ rad = ∆s/r                    (This is probably pretty useful!)

Of course you can convert from rad to degrees. 

Multiply degrees by π/180 to get radians

Multiply radians by 180/π to get degrees.

But, that would be annoying! Google it, if you want.

Sample 3: A thing is at a radius of 2 from a point and is moving in a circle. If it moves such that it's arc length is 4, what is its angular displacement? (Ans 2 rad)


It follows that, in a case where something is measured from a reference point (a line or angle or something), if that something moves a final angular displacement can be found (by mathing it) as…

∆θ = θf - θi

θ = θi  + ∆θ

This should remind you of one of the liner displacement formulas!

df = di + ∆d

Angular Velocity

Angular velocity: The amount that the angle changes in some period of time. That is to say, it is the angular displacement / elapsed time.

For instance, something with an angular velocity of 20° per second would turn 20° in 1 second, 40° in 2 seconds, 60° in 3 seconds… etc.

Other ways to describe angular velocity is to discuss revolutions per some period of time. The rate that car engines turn is reported in RPM or revolutions per minute. Revolutions per second are also normal.

Officially (SI UNITS) the units on angular velocity are radians per second  (rad/s)

It is handy to know that a circle is 360° around or 2π radians.

We need a formula!

Because of something to do with something or for some reason… Never mind.

The symbol for angular velocity is the Greek omega (not W or w!) ω

Recall that the change in time  (elapsed time) is

∆t = tf - ti
    or
∆t = t1 - t0

and angular displacement is

∆θ = θf - θi
    or
∆θ = θ1 - θ0


so we can say that 

ω = ∆θ/∆t


This can appear in other forms that mean the same thing…


ω = (θf - θi)/(tf - ti)
ω = (θ1 - θ0)/(t1 - t0)


Sample 1: A thing rotates 12° in 4 seconds. What is its angular velocity? (Ans. 3°/s)

Sample 2: A thing rotates 12 rad in 4 seconds. What is its angular velocity? (Ans. 3 rad/s)

Sample 2: A thing rotates 360 times in 1 minute (360 RPM). What is its angular velocity in degrees per second? (Ans 21,600°/s)

360 RPM is 60 rotations per second. Each rotation is 360°. Thus 

∆θ = 60 • 360°
∆t = 1

ω = ∆θ/∆t

The formula below can be rearranged to find the change in the angle:

ω = ∆θ/∆t

∆t•ω = ∆θ

Then, rearranged…

∆θ = ω∆t

This should remind you of a linear motion formula!

∆d = v∆t


Angular Displacement Part II

What if we took our angular displacement formula and did some math? That could be fun!

θ = θi  + ∆θ

∆θ = ω∆t

Let the magic happen!

θ = θi  + ω∆t


Wanna know a secret (that really isn't a secret)? Go to the bottom of this page!


Angular Acceleration

Angular acceleration: The amount that the rate at which angular velocity changes over some period of time. That is to say, it is the change in angular velocity / elapsed time.

Since we are using a for linear acceleration let's use a Greek a for angular acceleration—α

Where 

α is angular acceleration

∆ω is change in angular veloicty

∆t is elapsed time

α = ∆ω / ∆t

Let's do that math magic!

α = ∆ω / ∆t

∆ω = α•∆t

Pssttt… It's not REALY magic… 

If something has angular velocity to start with and it gets more, then the final angular velocity is…

ωf = ωi + ∆ω

and then…

ωf = ωi + ∆ω

∆ωα•∆t

ωf = ωi + α•∆t

You might be thinking of the linear kinematic equation for final velocity!

Summary

Angular displacement: The amount that the angle changes of from the initial position to the final position.

Angular displacement is sometimes represented by the letter phi φ. Angles are often represented by θ.

∆θ = θf - θi

φ = θf - θi 

θ = θi  + ∆θ 

θf  = θi  + ω∆t

In general, any angle θ measured in radians is defined by the formula

θ = s/r

where s is arc length and r is radius

that means that

∆θ rad = ∆s/r


Angular velocity: The amount that the angle changes in some period of time. That is to say, it is the angular displacement / elapsed time.

The symbol for angular velocity is the Greek omega (not W or w!) ω


ω = ∆θ/∆t 
 
∆θ = ω∆t 
 
ωf = ωi + α•∆t

Angular acceleration: The amount that the rate at which angular velocity changes over some period of time. That is to say, it is the change in angular velocity / elapsed time.

Since we are using a for linear acceleration let's use a Greek a for angular acceleration—α

α = ∆ω / ∆t 
 
∆ω = α•∆t

Not Really A Secret!

 So abut that final displacement thing…

Where X is an amount thing (displacement, velocity, cookies, money, pizza )and ∆t is time and r is rate the thing changes…

and where the subscript f is final amount and i is initial amount…

Xf = Xi + r∆t


EXAMPLE: Bob has 4 things. Every minute he gets 2 more things.  How many things will Bob have after 5 minutes.

Where X = things…

Find Xf where…

Xi = 4 things

r = 2 things/minute

∆t = 5 minutes

Xf = Xi + r∆t

X= 4 + 2•5

X= 4 + 10

X= 14

    

 

 


Wednesday, January 31, 2024

Strength of Chemical Bonds

 General Chemistry Index

Where are we going with this? This page will give the ability to use laboratory observations and data to compare and contrast ionic, covalent, network, metallic, polar, and non-polar substances with respect to constituent particles, strength of bonds, melting and boiling points, and conductivity; provide examples of each type.


Strength of Chemical Bonds / Bond Energy
Are all chemical bonds the same… 

Compounds are formed when two or more elements combine chemically in fixed, specific ratios. Combine… What?

Elements combine to form compounds by bonding to other elements—in fixed, specific ratios. They do this in several ways, both intramolecularly (strong) and intermolecularly (weaker).  (See also.)

Intramolecular bonds occur as either ionic or covalent (and some covalent bonds are polar).

When considering the strength of chemical bonds, it is convenient to rank bond strength by type of bond. However do thing this is a drastic over-simplification.

Aside from saying that intramolecular bonds are stronger than intermolecular bonds, we cannot say always this or that (it is chemistry, after all!).

"When a bond is strong, there is a higher bond energy because it takes more energy to break a strong bond" (Source, 2024). Thus, bond strength is actually a way of comparing bond energy. And bond energy is far from simple!

The following table shows the bond energy of various bonds:

Table 1: Average Bond Energies (kJ/mol)
Single Bonds Multiple Bonds
H—H
432
N—H
391
I—I
149
C = C
614
H—F
565
N—N
160
I—Cl
208
C ≡ C
839
H—Cl
427
N—F
272
I—Br
175
O = O
495
H—Br
363
N—Cl
200
    C = O*
745
H—I
295
N—Br
243
S—H
347
C ≡ O
1072
    N—O
201
S—F
327
N = O
607
C—H
413
O—H
467
S—Cl
253
N = N
418
C—C
347
O—O
146
S—Br
218
N ≡ N
941
C—N
305
O—F
190
S—S
266
C ≡ N
891
C—O
358
O—Cl
203
    C = N
615
C—F
485
O—I
234
Si—Si
340
   
C—Cl
339
    Si—H
393
   
C—Br
276
F—F
154
Si—C
360
   
C—I
240
F—Cl
253
Si—O
452
   
C—S
259
F—Br
237
       
    Cl—Cl
239
       
    Cl—Br
218
       
    Br—Br
193
       
*C == O(CO2) = 799


A cursory look will indicate that a lot of the ionic bonds are stronger than a lot of the single covalent bonds. But looking closer will reveal that not all ionic bonds are stronger than all covalent bonds

For instance, compare the Si-O bond (covalent) to the H-Cl (ionic) bond.

FURTHER, most of the double and triple covalent bonds are stronger (have higher bond energy) than most of the ionic bonds (c.f. C ≡ C ).

So what?

To rank bond strength by bond type proves to be a pretty bad idea. While there are tendencies, there is no all-fitting rule. In the end, the convenience of such an attempt must be sacrificed to accuracy.